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74. Electrophilic Terminal Arsinidene-Iron(0) Complexes with a Two-coordinated Arsenic Atom
M. K. Sharma, B. Neumann, H.-G. Stammler, D. M. Andrada, R. S. Ghadwal*
The electrophilic arsinidene complexes 5 and 6 featuring a two-coordinated arsenic atom have been isolated as crystalline solids. Complex 5 readily reacts with an NHC nucleophile (IMe4) to give the Lewis adduct 7.
72. Crystalline Divinyldiarsene Radical Cations and Dications
M. K. Sharma, S. Blomeyer, B. Neumann, H.-G. Stammler, M. van Gastel, A. Hinz, R. S. Ghadwal*
One-by-one electron oxidation of diarsenes [As2] featuring very efficient π-donor N-heterocyclic vinyl substituents with GaCl3 leads to the formation of radical cations [As2] and dications [As2] as crystalline solids. Experimental and computational studies revealed the delocalization of unpaired electron over the π-conjugated CAs2C framework.
73. Direct Functionalization of White Phosphorus with Anionic Dicarbenes and Mesoionic Carbenes: Facile Access to
D. Rottschäfer, S. Blomeyer, B. Neumann, H.-G. Stammler, R. S. Ghadwal*