2024

1. F. Ebeler, B. Neumann, H.-G. Stammler, Israel Fernández, R. S. Ghadwal*
   Structural snapshots of reversible carbon dioxide capture and (de)oxygenation at group 14 diradicaloids
   Journal of the American Chemical Society 2024, 146, 34979–34989.
   DOI: https://pubs.acs.org/doi/10.1021/jacs.4c15062
   
2. F. Ebeler, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, D. W. Szczepanik, R. S. Ghadwal*
   Annulated 1,4-disilabenzene-1,4-diide and dihydrogen splitting
   Journal of the American Chemical Society 2024, 146, 30584‒30595.
   DOI: https://pubs.acs.org/doi/10.1021/jacs.4c12127
   
3. A. Merschel, S. Heda, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
   Annulated carbocyclic gallylene and bis-gallylene with two-coordinated Ga(I) atoms
   Chemical Science 2024, 15, asap.
   DOI: https://doi.org/10.1039/D4SC06782G
   
4. A. Merschel, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
   Boosting the π-acceptor property of mesoionic carbenes by carbonylation with carbon monoxide
   Angewandte Chemie International Edition 2024, 63, e202318525.
   DOI: https://doi.org/10.1002/anie.202318525
   
5. H. Steffenfauseweh, D. Rottschäfer, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, B. de Bruin,* R. S. Ghadwal*
   Non-Kekulé meta-quinodimethane singlet diradicals based on classical N-heterocyclic carbenes
   Chemistry – A European Journal 2024, 30, e202403029
   DOI: https://doi.org/10.1002/chem.202403029
6. H. Steffenfauseweh, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, B. de Bruin, R. S. Ghadwal*
   N-Heterocyclic carbene analogues of Wittig hydrocarbon
   Chemistry – A European Journal 2024, 30, e202400879.
   DOI: https://doi.org/10.1002/chem.202400879
   
7. A. Merschel, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
   Access to a peri-annulated aluminium compound via C–H bond activation by a cyclic bis-aluminylene
   Chemistry – A European Journal 2024, 30, e202400293.
   DOI: https://doi.org/10.1002/chem.202400293
   
8. A. Merschel, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
   Ring-opening of 1,3-imidazole based mesoionic carbenes (iMICs) and ring-closing clicks: Facile access to iMIC-compounds
   Chemistry – A European Journal 2024, 30, e202303652.
   DOI: https://doi.org/10.1002/chem.202303652
   
9. F. Ebeler, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
   Divergent reactivity of a cyclic bis-hydridostannylene: A masked Sn(I) diradicaloid
   Chemistry – A European Journal 2024, 30, e202400382.
   DOI: https://doi.org/10.1002/chem.202400382
   
10. F. Ebeler, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Isolation of an anionic dicarbene-embedded Sn₂P₂ cluster and reversible CO₂ uptake
     Advanced Science 2024, 11, e202305545.
    DOI: https://doi.org/10.1002/advs.202305545.
    
    

    2023

11. A. Merschel, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Highly soluble cyclic organoalanes based on anionic dicarbenes
    Chemistry – A European Journal 2023, 29, e202301037.
    DOI: https://doi.org/10.1002/chem.202301037
    Highlighted in ChemistryViews
    
12. R. S. Ghadwal*
    1,3-Imidazole-based mesoionic carbenes and anionic dicarbenes: Pushing the limit of classical N-heterocyclic carbenes (Minireview)
    Angewandte Chemie International Edition 2023, 62, e202304665.
    DOI: https://doi.org/10.1002/anie.202304665
    
13. H. Steffenfauseweh, D. Rottschäfer, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, D. W. Szczepanik, R. S. Ghadwal*
    Isolation of an annulated 1,4-distibabenzene diradicaloid
    Angewandte Chemie International Edition 2023, 62, e202216003.
    DOI: https://doi.org/10.1002/anie.202216003 (Hot Paper

    Highlighted in ChemistryViews

14. A. Merschel, D. Rottschäfer, B. Neumann, H.-G. Stammler, M. Ringenberg, M. van Gastel, T. I. Demirer, D. M. Andrada, R. S. Ghadwal*
    Crystalline anions based on classical N-heterocyclic carbenes
    Angewandte Chemie International Edition 2023, 62, e202215244.
    DOI: https://doi.org/10.1002/anie.202215244 (Hot Paper)
    Highlighted in ChemistryViews
    Cover page Angewandte Chemie 135(5)/2023H.

    2022

15. Steffenfauseweh, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, D. M. Andrada, R. S. Ghadwal*
    Isolation of an arsenic diradicaloid with a cyclic C₂As₂-core
    Angewandte Chemie International Edition 2022, 61, e202207415.
    DOI: https://doi.org/10.1002/anie.202207415 (Hot Paper)

16. R. S. Ghadwal*
    Tuning the electronic properties of main-group species by N-heterocyclic vinyl (NHV) scaffolds
    Accounts of Chemical Research 2022, 55, 457–470.
    DOI: https://doi.org/10.1021/acs.accounts.1c00701

17. L. Weber,* F. Ebeler, R. S. Ghadwal*
    Advances and recent trends in dipnictenes chemistry
    Coordination Chemistry Review 2022, 461, 214499.
    DOI: https://doi.org/10.1016/j.ccr.2022.214499

18. A. Merschel, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Crystalline phosphino-functionalized mesoionic olefins (p-MIOs)
    Dalton Transactions 2022, 51, 8217–8222.
    DOI: https://doi.org/10.1039/D2DT01314B

19. F. Ebeler, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Mesoionic Dithiolates (MIDts) Derived from 1, 3‐Imidazole‐Based Anionic Dicarbenes (ADCs)
    Chemistry – A European Journal 2022, 28, e202200739.
    DOI: https://doi.org/10.1002/chem.202200739

    2021

20. D. Rottschäfer, T. Glodde, B. Neumann, H.-G. Stammler, D. M. Andrada, R. S. Ghadwal*
    Isolation of 1,4-dirasinine-1,4-diide and 1,4-diarsinine derivatives
    Angewandte Chemie International Edition 2021, 60, 15849–15853.
    DOI: https://doi.org/10.1002/anie.202105835

21. M. K. Sharma, D. Rottschäfer, B. Neumann, H.-G. Stammler, S. Danés, D. M. Andrada, M. van Gastel, A. Hinz, R. S. Ghadwal*
    Metalloradical cations and dications based on divinyldiphosphene and divinyldiarsene ligands
    Chemistry – A European Journal 2021, 27, 5803‒5809.
    DOI: https://doi.org/10.1002/chem.202100213

22. M. K. Sharma, D. Rottschäfer, T. Glodde, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    An open‐shell singlet Sn(I) diradical and H2 splitting
    Angewandte Chemie International Edition 2021, 60, 6414‒6418.
    DOI: https://doi.org/10.1002/anie.202017078 (Hot Paper)

23. M. K. Sharma, F. Ebeler, T. Glodde, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Isolation of a Ge(I) diradicaloid and dihydrogen splitting
    Journal of the American Chemical Society 2021, 143, 121‒125.
    DOI: https://doi.org/10.1021/jacs.0c11828

24. A. Merschel, T. Glodde, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Nickel catalyzed intramolecular 1,2‐aryl migration of mesoionic carbenes (iMICs)
    Angewandte Chemie International Edition 2021, 60, 2969–2973.
    DOI: https://doi.org/10.1002/anie.202014328

25. D. Rottschäfer, B. Neumann, H.-G. Stammler, T. Sergeieva, D. M. Andrada, R. S. Ghadwal*
    Isolation of a 16π-electrons 1,4-diphosphinine-1,4-diide with a planar C4P2 Ring
    Chemistry – A European Journal 2021, 27, 3055‒3064.
    DOI: https://doi.org/10.1002/chem.202003617

    2020

26. D. Rottschäfer, B. Neumann, H.-G. Stammler, D. M. Andrada, R. S. Ghadwal*
    Isolation of elusive electrophilic phosphinidene complexes with π-donor N-heterocyclic vinyl substituents
    Journal of Organic Chemistry 2020, 85, 14351‒14359.
    DOI: https://dx.doi.org/10.1021/acs.joc.0c00176

27. Rottschäfer, D. E. Fuhs, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Saturated NHC derived dichalcogen dications
    Zeitschrift für Anorganische und Allgemeine Chemie 2020, 646, 574‒579.
    DOI: https://doi.org/10.1002/zaac.202000189

28. M. K. Sharma, T. Glodde, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Distannabarrelenes with three coordinated Sn(II) atoms
    Chemistry – A European Journal 2020, 26, 11113‒11118.
    DOI: https://dx.doi.org/10.1002/chem.202001432
29. A. Merschel, D. Rottschäfer, B. Neumann, H.-G. Stammler, R. S. Ghadwal* Quantifying the electronic and steric properties of 1,3-imidazol-based mesoionic carbenes (iMICs)
    Organometallics 2020, 39, 1719‒1729.
    DOI: https://dx.doi.org/10.1021/acs.organomet.0c00045
    
30. M. K. Sharma, S. Blomeyer, T. Glodde, B. Neumann, H.-G. Stammler, A. Hinz, M. van Gastel, R. S. Ghadwal*
    Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications
    Chemical Science 2020, 11, 1975‒1984.
    DOI: http://dx.doi.org/10.1039/C9SC05598C
    
31. M. K. Sharma, S. Blomeyer, B. Neumann, H.-G. Stammler, A. Hinz, M. van Gastel, R. S. Ghadwal*

    Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications
    Chemical Communications 2020, 56, 3575‒3578.
    DOI: http://dx.doi.org/10.1039/D0CC00624F

32. D. Rottschäfer, T. Glodde, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    A crystalline C5-protonated 1,3-imidazol-4-ylidene
    Chemical Communications 2020, 56, 2027‒2030.
    DOI: https://doi.org/10.1039/D0CC00624F

    2019

33. M. K. Sharma, D. Rottschäfer, S. Blomeyer, B. Neumann, H.-G. Stammler, M. van Gastel, A. Hinz, R. S. Ghadwal*
    Diphosphene radical cations and dications with a π-conjugated C₂P₂C₂-framework
    Chemical Communications 2019, 55, 10408‒10411.
    DOI: http://dx.doi.org/10.1039/C9CC04701H

34. M. K. Sharma, B. Neumann, H.-G. Stammler, D. M. Andrada, R. S. Ghadwal*
    Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom
    Chemical Communications 2019, 55, 14669‒14672.
    DOI: http://dx.doi.org/10.1039/C9CC08630G
    
35. M. K. Sharma, S. Blomeyer, B. Neumann, H.-G. Stammler, M. van Gastel, A. Hinz, R. S. Ghadwal*
    Crystalline divinyldiarsene radical cations and dications
    Angewandte Chemie International Edition 2019, 58, 17599‒17603.
    DOI: https://doi.org/10.1002/anie.201909144
    
36. M. K. Sharma, S. Blomeyer, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Crystalline divinyldiarsenes and cleavage of the As=As bond
    Chemistry ‒ a European Journal 2019, 25, 8249‒8253.
    DOI: https://doi.org/10.1002/chem.201901857
37. D. Rottschäfer, M. K. Sharma, B. Neumann, H.-G. Stammler, D. M. Andrada, R. S. Ghadwal*
    A modular access to divinyldiphosphenes with a strikingly small HOMO-LUMO energy gap
    Chemistry – a European Journal 2019, 25, 8127‒8134.
    DOI: https://doi.org/10.1002/chem.201901204
    

38. D. Rottschäfer, B. Neumann, H.-G. Stammler, R. Kishi, M. Nakano, R. S. Ghadwal*
    A phosphorus analogue of p-quinodimethane with a planar P₄ ring: a metal-free diphosphorus source.
    Chemistry – a European Journal 2019, 25, 3244‒3247.
    DOI: https://doi.org/10.1002/chem.201805932

39. D. Rottschäfer, S. Blomeyer, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides
    Chemical Science 2019, 10, 11078‒11085.
    DOI: http://dx.doi.org/10.1039/C9SC04441H

40. R. S. Ghadwal*
    Stable carbon-centered radicals based on N-heterocyclic carbenes
    Synlett 2019, 30, 1765‒1775.
    DOI: https://doi.org/10.1055/s-0037-1611887

    2018

41. D. Rottschäfer, B. Neumann, H.-G. Stammler, M. van Gastel, R. Kishi, M. Nakano, R. S. Ghadwal*
    Diradical character enhancement by spacing: N-heterocyclic carbene analogues of Muller’s hydrocarbon.
    Chemistry – a European Journal 2018, 24, 16537‒16542.
    DOI: https://doi.org/10.1002/chem.201804524

42. D. Rottschäfer, N. K. T. Ho, B. Neumann, H.-G. Stammler, M. van Gastel, D. M. Andrada, R. S. Ghadwal*
    N-Heterocyclic carbene analogues of Thiele and Chichibabin hydrocarbons
    Angewandte Chemie International Edition 2018, 57, 5838‒5842.
    DOI: https://doi.org/10.1002/anie.201713346

43. D. Rottschäfer, B. Neumann, H.-G. Stammler, M. van Gastel, D. M. Andrada, R. S. Ghadwal*
    Crystalline radicals derived from classical N‐heterocyclic carbenes
    Angewandte Chemie International Edition 2018, 57, 4765‒4768.
    DOI: https://doi.org/10.1002/anie.201801596

44. D. Rottschäfer, B. Neumann, H.-G. Stammler, D. M. Andrada, R. S. Ghadwal*
    Kekulé diradicaloids derived from a classical N-heterocyclic carbene
    Chemical Science 2018, 9, 4970–4976.
    DOI: http://dx.doi.org/10.1039/C8SC01209A

45. D. Rottschäfer, F. Ebeler, T. Strothmann, B. Neumann, H.-G. Stammler, A. Mix, R. S. Ghadwal*
    The viability of C5-protonated- and C4,C5-ditopic carbanionic abnormal NHCs: A new dimension in NHC chemistry
    Chemistry ‒ a European Journal 2018, 24, 3716‒3720.
    DOI: https://doi.org/10.1002/chem.201800260

46. D. Rottschäfer, S. Blomeyer, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    Silylene-functionalized N-heterocyclic carbene (Si-NHC)
    Chemistry ‒ a European Journal 2018, 24, 380‒387.
    DOI: https://doi.org/10.1002/chem.201703530
    Highlighted as Cover page and authors profile

    2017

47. D. Rottschäfer, B. Neumann, H.-G. Stammler, R. S. Ghadwal*
    N-Heterocyclic Vinylidene-Stabilized Phosphorus Biradicaloid
    Chemistry ‒ a European Journal 2017, 23, 9044‒9047.
    DOI: https://doi.org/10.1002/chem.201702433

48. N. K. T. Ho, S. O. Reichmann, D. Rottschäfer, R. Herbst-Irmer, R. S. Ghadwal*
    Expanding the scope of Cu(I) catalyzed “Click Chemistry” with abnormal NHCs: Three-fold click to tris-triazoles
    Catalysts 2017, 7, 262.
    DOI: https://doi.org/10.3390/catal7090262

49. N. K. T. Ho, B. Neumann, H.-G. Stammler, V. H. Menezes da Silva, D. G. Watanabe, A. A. C. Braga, R. S. Ghadwal*
    Nickel-catalysed direct C2-arylation of N-heterocyclic carbenes
    Dalton Transactions 2017, 46, 12027‒12031.
    DOI: https://doi.org/10.1039/C7DT03099A

50. R. S. Ghadwal,* D. Rottschäfer, D. M. Andrada, G. Frenking, C. J. Schürmann, H.-G. Stammler
    Normal-to-abnormal rearrangement of an N-heterocyclic carbene with a silylene transition metal complex
    Dalton Transactions 2017, 46, 7791‒7799.
    DOI: https://doi.org/10.1039/C7DT01199G

51. R. S. Ghadwal,*J.-H. Lamm, D. Rottschäfer, C. J. Schürmann, S. Demeshko
    Facile routes to abnormal-NHC-cobalt(II) complexes
    Dalton Transactions 2017, 46, 7664‒7667.
    DOI: https://doi.org/10.1039/C7DT01778B
    Highlighted in ChemistryViews

    2016

52. D. Rottschäfer, C. J. Schürmann, J.-H. Lamm, A. N. Paesch, B. Neumann, R. S. Ghadwal*
    Abnormal-NHC palladium(II) complexes: Rational synthesis, structural elucidation, and catalytic activity
    Organometallics 2016, 35, 3421‒3429.
    DOI: http://dx.doi.org/10.1021/acs.organomet.6b00662

53. N. B. Sharma, J. Shahai, R. S. Ghadwal, A. Singh, E. Jeanneau, S. Mishra
    Homometallic glycolates containing hydroxyl functionality for anchoring another metal: synthesis and characterization of heterometallic alkoxide–glycolates of Ti and Zr incorporating Al and Nb
    Journal of Coordination Chemistry 2016, 69, 135‒148.
    DOI: http://dx.doi.org/10.1080/00958972.2015.1112900

54. R. S. Ghadwal, A. P. Singh, A. Singh
    Synthesis and spectroscopic characterization of trimethylsilicon- And tributyltin-tris(glycolato)niobates
    Journal of the Indian Chemical Society 2016, 93, 965‒970.

55. R. S. Ghadwal,* D. Rottschäfer, C. J. Schürmann
    Expedient access to normal- and abnormal- N-heterocyclic carbene (NHC) magnesium compounds from imidazolium salts
    Zeitschrift für Anorganische und Allgemeine Chemie 2016, 642, 1236‒1240.
    DOI: https://doi.org/10.1002/zaac.201600308

56. R. S. Ghadwal*
    Carbon-based two electron sigma-donor ligands beyond classical N-heterocyclic carbenes
    Dalton Transactions 2016, 45, 16081‒16095.
    DOI: https://doi.org/10.1039/C6DT02158A

    2015

57. R. S. Ghadwal,* C. J. Schürmann, D. M. Andrada, G. Frenking
    Mono- and di-cationic hydrido boron compounds
    Dalton Transactions 2015, 44, 14359‒14367.
    DOI: https://doi.org/10.1039/C5DT02237A

58. R. S. Ghadwal,* S. O. Reichmann, R. Herbst-Irmer
    Palladium-catalyzed direct C2-arylation of an N-heterocyclic carbene: An atom-economic route to mesoionic carbene ligands
    Chemistry ‒ a European Journal 2015, 21, 4247‒4251.
    DOI: https://doi.org/10.1002/chem.201405923

    2014

59. R. S. Ghadwal,* C. J. Schürmann, F. Engelhardt, C. Steinmetzger
    Unprecedented borylene insertion into a C–N bond
    European Journal of Inorganic Chemistry 2014, 4908‒4908.
    DOI: http://dx.doi.org/10.1002/ejic.201402872
    Highlighted as Cover page and authors profile

60. R. S. Ghadwal, A. Singh
    Synthesis and spectroscopic characterisation of heterobimetallic oxovanadimn(V) 2,5-dimethyl-2,5-hexanediolate-alkoxides
    Journal of the Indian Chemical Society 2014, 91, 2051‒2055.

61. R. S. Ghadwal,* S. O. Reichmann, E. Carl, R. Herbst-Irmer
    Synthesis and structural investigation of R2Si (R = Me, Ph) bridged di-N-heterocyclic carbenes
    Dalton Transactions 2014, 43, 13704‒13710.
    DOI: https://doi.org/10.1039/C4DT01681E

    2013

62. R. S. Ghadwal,* S. O. Reichmann, F. Engelhardt, A. M. Andrada, G. Frenking
    Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3
    Chemical Communications 2013, 49, 9440‒9442.
    DOI: https://doi.org/10.1039/C3CC45652H

63. R. S. Ghadwal,* R. Azhakar, H. W. Roesky
    Dichlorosilylene: a high temperature transient species to an indispensable building block
    Accounts of Chemical Research 2013, 46, 444‒456.
    DOI: https://doi.org/10.1021/ar300196u

64. R. S. Ghadwal,* R. Azhakar, K. Pröpper, B. Dittrich, M. John
    Selective functionalization of a bis-silylene
    Chemical Communications 2013, 49, 5987‒5989.
    DOI: https://doi.org/10.1039/C3CC43199A

65. R. Azhakar, R. S. Ghadwal,* H. W. Roesky, R. A. Mata, H. Wolf, R. Herbst-Irmer, D. Stalke
    Reaction of N-heterocyclic silylenes with thioketone: Formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems
    Chemistry ‒ a European Journal 2013, 19, 3715‒3720.
    DOI: https://doi.org/10.1002/chem.201203242

66. R. Azhakar, R. S. Ghadwal,* H. W. Roesky, J. Hey, L. Krause, D. Stalke
    Mixed valence η6-arene cobalt(I) and cobalt(II) compound
    Dalton Transactions 2013, 42, 10277‒10281.
    DOI: https://doi.org/10.1039/C3DT50939G

    2012 (PostDoc)

67. A. P. Singh, R. S. Ghadwal,* H. W. Roesky, J. J. Holstein, B. Dittrich, J.-P. Demers, V. Chevelkov, A. Lange
    Lewis base mediated dismutation of trichlorosilane
    Chemical Communications 2012, 48, 7574‒7576.
    DOI: https://doi.org/10.1039/C2CC33835A

68. P. P. Samuel, R. Azhakar, R. S. Ghadwal,* S. S. Sen, H. W. Roesky, M. Granitzka, J. Matussek, R. Herbst-Irmer, D. Stalke
    Stable silaimines with three- and four-coordinate silicon atoms
    Inorganic Chemistry 2012, 51,11049‒11054.
    DOI: https://doi.org/10.1021/ic301543y

69. R. S. Ghadwal,* R. Azhakar, H. W. Roesky, K. Pröpper, B. Dittrich, C. Goedecke, G. Frenking
    Donor-acceptor stabilized silaformyl chloride
    Chemical Communications 2012, 48, 8186‒8188.
    DOI: https://doi.org/10.1039/C2CC32887A

70. R. Azhakar, H. W. Roesky, R. S. Ghadwal,* J. J. Holstein, B. Dittrich
    An access to base-stabilized three-membered silicon heterocycles
    Dalton Transactions 2012, 41, 9601‒9603.
    DOI: https://doi.org/10.1039/C2DT31326J

71. R. Azhakar, R. S. Ghadwal,* H. W. Roesky, H. Wolf, D. Stalke
    A debut for base stabilized monoalkylsilylenes
    Chemical Communications 2012, 48, 4561‒4563.
    DOI: https://doi.org/10.1039/C2CC31041D

72. R. Azhakar, R. S. Ghadwal,* H. W. Roesky, H. Wolf, D. Stalke
    Stabilization of low valent silicon fluorides in the coordination sphere of transition metals
    Journal of the American Chemical Society 2012, 134, 2423‒2428.
    DOI: https://doi.org/10.1021/ja210697p

73. R. Azhakar, R. S. Ghadwal,* H. W. Roesky, H. Wolf, D. Stalke
    Facile access to the functionalized N-donor stabilized silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)
    Organometallics 2012, 31, 4588‒4592.
    DOI: https://doi.org/10.1021/om3003762

74. R. Azhakar, R. S. Ghadwal,* H. W. Roesky, J. Hey, D. Stalke
    Facile access to transition-metal-carbonyl complexes with an amidinate-stabilized chlorosilylene Ligand
    Chemistry ‒ an Asian Journal 2012, 7, 528‒533.
    DOI: https://doi.org/10.1002/asia.201100722

75. R. Azhakar, R. S. Ghadwal, H. W. Roesky, J. Hey, D. Stalke
    Double N-H bond activation of N,N‘-bis-substituted hydrazines with stable N-heterocyclic silylene
    Dalton Transactions 2012, 41, 1529‒1533.
    DOI: https://doi.org/10.1039/C1DT11708D

76. R. Azhakar, R. S. Ghadwal,* H. W. Roesky, M. Granitzka, D. Stalke
    Reactivity studies of a stable N-heterocyclic silylene with triphenylsilanol and pentafluorophenol
    Organometallics 2012, 31, 5506‒5510.
    DOI: https://doi.org/10.1021/om300476q

    2011 (PostDoc)
    

77. S. S. Sen, R. S. Ghadwal, D. Kratzert, D. Stern, H. W. Roesky, D. Stalke
    Synthesis and structure of [{PhC(NtBu)2}2Ge2(μ-S)2Cl2] and a germanium dithiocarboxylate analogue
    Organometallics 2011, 30, 1030‒1033.
    DOI: https://doi.org/10.1021/om101074j

78. P. W. Percival, J. C. Brodovitch, M. Mozafari, A. Mitra, R. West, R. S. Ghadwal, R. Azhakar, H. W. Roesky
    Free radical reactivity of mono- and dichlorosilylene with muonium
    Chemistry ‒ a European Journal 2011, 17, 11970‒11973.
    DOI: https://doi.org/10.1002/chem.201102405

79. R. S. Ghadwal, H. W. Roesky, K. Pröpper, B. Dittrich, S. Klein, G. Frenking
    A dimer of silaisonitrile with two-coordinate silicon atoms
    Angewandte Chemie International Edition 2011, 50, 5374‒5378.
    DOI: https://doi.org/10.1002/anie.201101320

80. R. S. Ghadwal, K. Pröpper, B. Dittrich, P.G. Jones, H. W. Roesky
    Neutral pentacoordinate silicon fluorides derived from amidinate, guanidinate, and triazapentadienate ligands and base-induced disproportionation of Si2Cl6 to stable silylenes
    Inorganic Chemistry 2011, 50, 358‒364.
    DOI: https://doi.org/10.1021/ic1020548

81. R. S. Ghadwal,* R. Azhakar, H. W. Roesky, K. Pröpper, B. Dittrich, S. Klein, G. Frenking
    Donor-acceptor-stabilized silicon analogue of an acid anhydride
    Journal of the American Chemical Society 2011, 133, 17552‒17555.
    DOI: https://doi.org/10.1021/ja206702e

82. R. S. Ghadwal,* R. Azhakar, K. Propper, J. J. Holstein, B. Dittrich, H. W. Roesky
    N-Heterocyclic carbene stabilized dichlorosilylene transition-metal complexes of V(I), Co(I), and Fe(0)
    Inorganic Chemistry 2011, 50, 8502‒8508.
    DOI: https://doi.org/10.1021/ic201096c

83. R. Azhakar, R. S. Ghadwal, H. W. Roesky, J. Hey, D. Stalke
    Reactions of stable N-heterocyclic silylenes with ketones and 3,5-di-tert-butyl-o-benzoquinone
    Organometallics 2011, 30, 3853‒3858.
    DOI: https://doi.org/10.1021/om200388a

    2010 (PostDoc)

84. J. Li, S. Merkel, J. Henn, K. Meindl, A. Doring, H. W. Roesky, R. S. Ghadwal, D. Stalke
    Lewis-base-stabilized dichlorosilylene: A two-electron σ-donor ligand
    Inorganic Chemistry 2010, 49, 775‒777.
    DOI: https://doi.org/10.1021/ic9023162

85. R. S. Ghadwal, S. S. Sen, H. W. Roesky, M. Granitzka, D. Kratzert, S. Merkel, D. Stalke
    Convenient access to monosilicon epoxides with pentacoordinate silicon
    Angewandte Chemie International Edition 2010, 49, 3952‒3955.
    DOI: https://doi.org/10.1002/anie.201000835

86. R. S. Ghadwal, H. W. Roesky, C. Schulzke, M. Granitzka
    N-Heterocyclic carbene stabilized dichlorosilaimine IPr·Cl2Si:NR
    Organometallics 2010, 29, 6329‒6333.
    DOI: https://doi.org/10.1021/om100737v

87. R. S. Ghadwal, H. W. Roesky, S. Merkel, D. Stalke
    Ambiphilicity of dichlorosilylene in a single molecule
    Chemistry ‒ a European Journal 2010, 16, 85‒88.
    DOI: https://doi.org/10.1002/chem.200902930

88. R. S. Ghadwal, H. W. Roesky, M. Granitzka, D. Stalke
    A facile route to functionalized N-heterocyclic carbenes (NHCs) with NHC base-stabilized dichlorosilylene
    Journal of the American Chemical Society 2010, 132, 10018‒10020.
    DOI: https://doi.org/10.1021/ja104386g

    2009 (PostDoc)

89. N. B. Sharma, R. S. Ghadwal, A. Singh
    Synthesis and spectroscopic structural elucidation of some novel heterobimetallic complexes of monoorganotin(IV)
    Main Group Metal Chemistry 2009, 32, 253‒262.
    DOI: https://doi.org/10.1515/MGMC.2009.32.5.253

90. R. S. Ghadwal, S. S. Sen, H. W. Roesky, G. Tavcar, S. Merkel, D. Stalke
    Neutral penta- and hexacoordinate N-heterocyclic carbene complexes derived from SiX4 (X = F, Br)
    Organometallics 2009, 28, 6374‒6377.
    DOI: https://doi.org/10.1021/om9007696

91. R. S. Ghadwal, H. W. Roesky, S. Merkel, J. Henn, D. Stalke
    Lewis base stabilized dichlorosilylene
    Angewandte Chemie International Edition 2009, 48, 5683‒5686.
    DOI: https://doi.org/10.1002/anie.200901766

92. R. S. Ghadwal, H. W. Roesky, R. Herbst-Irmer, P. G. Jones
    N-Heterocyclic carbene adducts of aluminum triiodide
    Zeitschrift für Anorganische und Allgemeine Chemie 2009, 635, 431‒433.
    DOI: https://doi.org/10.1002/zaac.200801350

    2004‒2008 (PhD)

93. N. B. Sharma, R. S. Ghadwal, A. Singh
    Synthesis and characterisation of some novel seven-membered heterocyclic antimony(III) glycolate complexes
    Main Group Metal Chemistry 2008, 31, 217‒225.
    DOI: https://doi.org/10.1515/MGMC.2008.31.5.217

94. R. S. Ghadwal, A. Singh
    Synthesis and spectroscopic properties of some new metallatranes
    Indian Journal of Chemistry 2007, 46A, 768‒771.
    URL: http://nopr.niscair.res.in/handle/123456789/1195

95. R. S. Ghadwal, A. Singh
    Synthesis and spectroscopic characterisation of a new class of heterobimetallic homoleptic diethanolaminate complexes of niobium(V) and tantalum(V)
    Journal of Chemical Research 2006, 451‒455.
    DOI: https://doi.org/10.3184/030823406777980664

96. R. S. Ghadwal, A. Singh
    Synthesis and spectroscopic properties of homo- and heterobimetallic complexes of oxovanadium(V)
    Journal of Chemical Sciences 2006, 118, 165‒170.
    DOI: https://doi.org/10.1007/BF02708468

97. R. S. Ghadwal, A. Singh
    Synthesis and spectroscopic characterization of mixed ligand complexes of oxovanadium(V)
    Indian Journal of Chemistry 2006, 45A, 2644‒2649.
    URL: http://nopr.niscair.res.in/handle/123456789/18007

98. R. S. Ghadwal, R. C. Mehrotra, A. Singh
    Synthesis and spectroscopic [IR, NMR (1H, 27Al and 51V)] characterization of heterobimetallic glycolate- and diethanolaminate-isopropoxide complexes of aluminum
    Main Group Metal Chemistry 2006, 29, 1‒9.
    DOI: https://doi.org/10.1515/MGMC.2006.29.1.1

99. R. S. Ghadwal, R. C. Mehrotra, A. Singh
    Synthesis and spectroscopic properties of the first series of heteronuclear derivatives containing organosilicon/organotin (IV) and oxovanadium (V) moieties
    Phosphorus, Sulfur, Silicon and the Related Elements 2006, 181, 113‒123.
    DOI: https://doi.org/10.1080/104265090969036

100. N. B. Sharma, R. S. Ghadwal, A. Singh
     Preparation and characterization of heteronuclear mixed ligand complexes of aluminum containing organosilicon/organotin moieties
     Main Group Metal Chemistry 2005, 28, 173‒183.
     DOI: https://doi.org/10.1515/MGMC.2005.28.4.173

101. R. S. Ghadwal, A. Singh, R. C. Mehrotra
     Synthesis and characterisation of heterobimetallic N-(hydroxyethyl)salicylaldiminate-isopropoxide complexes of oxovanadium(V)
     Transition Metal Chemistry 2005, 30, 268‒272.
     DOI: https://doi.org/10.1007/s11243-004-3766-8

102. R. S. Ghadwal, A. Singh
     Synthesis and characterization of heterobimetallic N-substituted diethanolaminate-alkoxides of niobium(V)
     Indian Journal of Chemistry 2005, 44A, 2439‒2444.
     URL: http://nopr.niscair.res.in/handle/123456789/20239

103. R. S. Ghadwal, R. C. Mehrotra, A. Singh
     Preparation and spectroscopic characterization of a series of heterobimetallic N-phenyldiethanolaminate-alkoxide derivatives of oxovanadium(V)
     Journal of Chemical Research 2005, 352‒355.
     DOI: https://doi.org/10.3184/0308234054506857

104. R. S. Ghadwal, R. C. Mehrotra, A. Singh
     Synthesis and spectroscopic characterization of two different types of heterobimetallic glycolate complexes of niobium(V)
     Transition Metal Chemistry 2005, 30, 836‒844.
     DOI: https://doi.org/10.1007/s11243-005-6258-6

105. R. S. Ghadwal, R. C. Mehrotra, A. Singh
     Preparation and spectroscopic [IR, NMR (1H, 11B, 27Al, 51V)] characterisation of new types of heteronuclear derivatives of aluminium and boron containing bis(2,5-dimethyl-2,5-hexanediolato)oxovanadium(V) group
     Main Group Metal Chemistry 2004, 27, 199‒209.
     DOI: https://doi.org/10.1515/MGMC.2004.27.4.199

106. R. S. Ghadwal, M. Sharma, A. Singh, R. C. Mehrotra
     Synthesis and spectroscopic characterisation of six-coordinate complexes of oxovanadium(V)
     Transition Metal Chemistry 2004, 29, 419‒424.
     DOI: https://doi.org/10.1023/B:TMCH.0000027460.70418.98

107.